Pioneer is a village in Williams County, Ohio, United States. The population was 1,429 at the 2020 census. Pioneer was platted in 1853. A post office has been in operation at Pioneer since 1851. From 1903, the village was the terminus of an electric interurban passenger railroad from Toledo called the Toledo and Western Railway, which was hoping to …Pioneer is a village in Williams County, Ohio, United States. The population was 1,429 at the 2020 census. Pioneer was platted in 1853. A post office has been in operation at Pioneer since 1851. From 1903, the village was the terminus of an electric interurban passenger railroad from Toledo called the Toledo and Western Railway, which was hoping to become a link in an electric rail service from that city to Chicago but which got no further. The line closed to passengers in 1933 but continued freight service until 1943, from 1934 as the Pioneer and Fayette Railroad. This was only formally abandoned in 1991.
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